A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for a,b-unsaturated alcohols; the reactions are slow.

Catalytic Aerobic Oxidation of Allylic Alcohols to Carbonyl Compounds under Mild Conditions

TONUCCI, Lucia;NICASTRO, Marco;D'ALESSANDRO, Nicola;BRESSAN, Mario;D'AMBROSIO, PRIMIANO;
2009-01-01

Abstract

A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for a,b-unsaturated alcohols; the reactions are slow.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11564/140952
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