The results of the reaction between ethyl diazoacetate and carbonyl compounds catalysed by lanthanide triflates are described, Aldehydes, and alpha-unsubstituted and alpha-monosubstituted cyclohexanones react to give the selective formation of alpha,beta-epoxy esters (glycidic esters), whereas other ketones are unreactive,
The Synthesis of Solvent-Free Glycidic Esters from Diazoesters and Carbonyl Compounds Catalysed by Lanthanide Triflates
EPIFANO, Francesco;
2002-01-01
Abstract
The results of the reaction between ethyl diazoacetate and carbonyl compounds catalysed by lanthanide triflates are described, Aldehydes, and alpha-unsubstituted and alpha-monosubstituted cyclohexanones react to give the selective formation of alpha,beta-epoxy esters (glycidic esters), whereas other ketones are unreactive,File in questo prodotto:
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