Treatment of a series of β,γ-unsaturated α-diazo-β-ketoesters with dirhodium tetraacetate results in the formation of rhodium carbenoids which undergo further skeletal rearrangement to produce substituted malonates.
Vinylogous Wolff Rearrangement of a,b-Unsaturated a-Diazo-b-ketoesters: a Novel Method for the Preparation of Substituted Malonates
EPIFANO, Francesco;
1995-01-01
Abstract
Treatment of a series of β,γ-unsaturated α-diazo-β-ketoesters with dirhodium tetraacetate results in the formation of rhodium carbenoids which undergo further skeletal rearrangement to produce substituted malonates.File in questo prodotto:
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