By the appropriate choice of the reaction conditions Oxone® produces the ring cleavage of α-nitrocycloalkanones affording good yields of α,ω-dicarboxylic acids and α,ω-dicarboxylic acid monomethyl esters, respectively, regardless the ring size and/or the presence of an alkyl group as substituent.
A new, modulated, oxidative ring cleavage of α-nitrocycloalkanones by Oxone®: Synthesis of α,ω-dicarboxylic acids and α,ω-dicarboxylic acid monomethyl esters
EPIFANO, Francesco;
1998-01-01
Abstract
By the appropriate choice of the reaction conditions Oxone® produces the ring cleavage of α-nitrocycloalkanones affording good yields of α,ω-dicarboxylic acids and α,ω-dicarboxylic acid monomethyl esters, respectively, regardless the ring size and/or the presence of an alkyl group as substituent.File in questo prodotto:
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