Rate coefficients for the relaxation of vibrational excited oxygen molecules, including both vibration-to-vibration (V-V) and vibration-to-translation (V-T) energy exchange, have been calculated using a semiclassical method and a new potential energy surface for a large interval of initial vibrational quantum numbers (1 ≤ v ≤29) in the temperature range between 50 and 1000 K..
Vibrational energy transfer in molecular oxygen collisions
COLETTI, Cecilia;
2002-01-01
Abstract
Rate coefficients for the relaxation of vibrational excited oxygen molecules, including both vibration-to-vibration (V-V) and vibration-to-translation (V-T) energy exchange, have been calculated using a semiclassical method and a new potential energy surface for a large interval of initial vibrational quantum numbers (1 ≤ v ≤29) in the temperature range between 50 and 1000 K..File in questo prodotto:
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