A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for a,b-unsaturated alcohols; the reactions are slow.
Catalytic Aerobic Oxidation of Allylic Alcohols to Carbonyl Compounds under Mild Conditions
TONUCCI, Lucia;NICASTRO, Marco;D'ALESSANDRO, Nicola;BRESSAN, Mario;D'AMBROSIO, PRIMIANO;
2009-01-01
Abstract
A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for a,b-unsaturated alcohols; the reactions are slow.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
