The high oxidizing power of excited states allows the preparation of radical cations in solution under mild conditions. These species often fragment competitively with back electron transfer and yield a radical and a cation. The selectivity of the process and the novel chemical reactions obtained is this ways are discussed through examples mainly using aryl nitriles as acceptors and benzyl derivatives as donors. © 1993.

Radical cations: generation by photochemical electron transfer and fragmentation

Nicola d'Alessandro
1993

Abstract

The high oxidizing power of excited states allows the preparation of radical cations in solution under mild conditions. These species often fragment competitively with back electron transfer and yield a radical and a cation. The selectivity of the process and the novel chemical reactions obtained is this ways are discussed through examples mainly using aryl nitriles as acceptors and benzyl derivatives as donors. © 1993.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11564/704999
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